It's the southeastern-most point on the Capital Wasteland map. Rivet City is a large settlement on board a split-in-half aircraft carrier from long before the nuclear war. If for some reason you've never been to Rivet City, now's as good a time as any to get there, since it's an important location on your main quest. Let's start with Flak, who is located all the way down in Rivet City. You can be violent with each character you need to capture, but ultimately you'll need to stun them with the Mesmetron long enough to get the slave collar on them. You'll need to use the Mesmetron weapon Grouse gives you, along with four Slave Collars. Nonetheless, the list of four characters is given, along with their current location, which can be seen on the Pip-Boy map. Sounds good to us! Unless you're playing a good character, of course, at which point that simply won't jive with your style. It appears he wants you to capture four 'VIP' slaves, and he'll split the commission with you for each of them. Thankfully, once entrance to Paradise Falls is secured, you can speak to Grouse again and get some work from him. If you're a chaotic evil character, you should be able to get into the slaver compound without much of an issue, but everyone else is going to have to cough up a staggering 500 Bottle Caps. Grouse is guarding the entrance to the slaver safe-haven, and he'll instantly start talking crap to you as you arrive. When you arrive at Paradise Falls for the first time, you're going to be greeted by a character named Grouse. Preferably, it should be undertaken as soon as you arrive at Paradise Falls (which is located towards the northwest end of the Capital Wasteland), that way you have the option of dealing with the slavers however you want once the deed is done. You need to do this side quest before you deal with Paradise Falls one way or another.

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Fallout 4 slave collar